Dogfood `str_split_once()`
Part of https://github.com/rust-lang/rust/issues/74773.
Beyond increased clarity, this fixes some instances of a common confusion with how `splitn(2)` behaves: the first element will always be `Some()`, regardless of the delimiter, and even if the value is empty.
Given this code:
```rust
fn main() {
let val = "...";
let mut iter = val.splitn(2, '=');
println!("Input: {:?}, first: {:?}, second: {:?}", val, iter.next(), iter.next());
}
```
We get:
```
Input: "no_delimiter", first: Some("no_delimiter"), second: None
Input: "k=v", first: Some("k"), second: Some("v")
Input: "=", first: Some(""), second: Some("")
```
Using `str_split_once()` makes more clear what happens when the delimiter is not found.
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